Two low-permittivity melilite ceramics in the SrO-MO-GeO2 (M = Mg,Zn) system and their temperature stability through compositional modifications

Two melilite ceramics Sr₂AGe₂O₇ (A = Mg, Zn) with low permittivity were prepared by a solid-state reaction method. The crystal structure and microstructure of the ceramics were characterized by X-ray diffraction, transmission electron microscopy, Raman spectroscopy, and scanning electron microscopy. Both ceramics crystallized in a single melilite structure with a tetragonal space group P-42m (113) and exhibited homogeneous microstructures. Optimum microwave dielectric properties with relative permittivity (ε_r) of 8.56, quality factor (Q × f) of 28,800 GHz, and temperature coefficient of resonance frequency (τ_f) of −70.5 ppm/°C were obtained in Sr₂MgGe₂O₇ sintered at 1330 °C. Sr₂ZnGe₂O₇ possessed ε_r of 8.81, Q × f of 35,700 GHz, and τ_f of −84.4 ppm/°C when sintered at 1290 °C. Thermal stability of resonance frequency was accessible when the negative τ_f values of Sr₂AGe₂O₇ were adjusted after the formation of composite ceramics with CaTiO₃.     

湿法磷酸净化脱砷的研究现状

随着食品、医药及电子行业的不断发展，磷酸及磷酸盐的市场需求量不断增大，并且对磷酸的品质要求也越来越高，尤其是对湿法磷酸中砷杂质的要求，湿法磷酸中砷的含量将直接影响其在磷精细化工领域的应用，因此湿法磷酸中砷的高效、安全去除是亟待解决的一大难题。本文主要对湿法净化磷酸脱砷技术的研究情况进行综述，比较了几种湿法净化磷酸脱砷工艺的优缺点，介绍了较常见的化学沉淀法、结晶法，以及新兴的电沉积法、垂直区域熔融法和微反应器脱砷工艺的应用前景，并指出这些新兴的脱砷工艺将成为今后湿法磷酸的净化脱砷的发展方向，如能解决将这些脱砷工艺在实际中的问题，将会对磷酸工业的发展提供一个更有力的支持。     

25CrNi2MoV钢的微动磨损性能

采用微动摩擦磨损试验机在干摩擦条件下对新型高速重载传动轴用25CrNi2MoV钢进行微动磨损试验,研究了不同载荷(50~200N)和频率(15~30Hz)下该钢的微动磨损性能。结果表明:在频率为20Hz条件下,当载荷由50N增至200N时,25CrNi2MoV钢的平均摩擦因数由0.766减至0.661,磨损体积由19.65×10^-3 mm^3增至75.83×10^-3 mm^3;在载荷为30N条件下,当频率由15Hz增至30Hz时,平均摩擦因数由0.790增至0.905,磨损体积由11.43×10^-3 mm^3增至23.88×10^-3 mm^3;在不同试验参数下,25CrNi2MoV钢磨损表面均出现了氧化和犁沟现象,磨损机制包含氧化磨损和磨粒磨损;在频率为20Hz条件下,载荷为50,100N时,25CrNi2MoV钢的磨损机制以黏着磨损为主,载荷为150,200N时,主要磨损机制为疲劳磨损;在载荷为30N条件下,频率为15~25Hz时,磨损机制以磨粒磨损为主,当频率增至30Hz时,磨损机制以疲劳磨损为主。     

大统矿业超高水充填开采制浆系统设计研究

煤炭作为我国的主要能源，在国民经济发展中具有不可取代的作用。矿井面临资源枯竭的困境时，尽可能多地采出煤炭是企业存续发展的当务之急。山东省兖州市大统矿业有限公司杨庄煤矿九采区3煤层1997—2005年进行了开采，由于受当时设备和技术的限制，仅回采一分层2.2 m。为挖掘企业潜力，充分利用煤炭资源，采用超高水充填法开采剩余分层和浅部煤炭资源。结合矿井实际情况提出适应矿井的高水充填系统布置方案，在地面建设制浆站，通过专门的设备将材料骨料制成浆液，然后运用管路将浆液输送至采空区进行充填。超高水材料制浆充填系统可服务于九采区全部充填工作面，每小时制浆生产能力为320 m³，每天生产1班8 h，约2 500 m³ 可以满足2个工作面的充填开采需要，极大提高了制浆充填效率，取得了良好的效果和经济社会效益。     

Physicochemical characteristics,antioxidant capacity and thermodynamic properties of purple-fleshed potatos dried by radio frequency energy

Abstract

The impacts of using radio frequency (RF) energy to dry purple-fleshed potatoes were investigated and compared to infrared radiation (IR) and microwave (MW) drying techniques. The gelatinization rate, color, flavor, morphological, and structural characteristics, thermodynamic properties, as well as antioxidant capacity were examined. The results indicated that the drying time of RF (70?min) and MW (21?min) were shorter than IR (105?min). The gelatinization ratio of MW, RF, and IR were 94.4?±?2.0, 88.3?±?1.4, and 64.5?±?1.1%, respectively. The degree of crystallization of purple-fleshed potato powder decreased with all three drying methods. RF-dried potatoes were able to retain higher polyphenols (loss rate: 4.3%), total anthocyanin (3.7%), and total flavonoid content (35.1%), whereas IR showed the lowest retention. The content of polyphenols also decreased significantly. Furthermore, after RF heating, the scavenging of free radicals was higher compared to MW and IR.     

煤巷过断层破碎带施工工艺与支护技术实践

W1313回风顺槽在里程332 m处揭露正断层,对此采取了调整巷道顶板锚网索支护参数,采用圆木大板棚复合支护等措施,并加强了顶板、通风、掘锚机破岩、爆破作业和作业人员的安全管理,确保工作面过断层破碎带时的安全施工。     

A variational approach for free vibrating micro-rods with classical and non-classical new boundary conditions accounting for nonlocal strengthening and temperature effects

Abstract

Transverse vibration of a circular cross sectional micro-rod subjected to a new kind of boundary constraints with elastic torsional springs is presented based on nonlocal elasticity. A nonlocal strengthening beam model is utilized and the effect of temperature changing is taken into consideration. The variational method and Hamilton’s principle are applied to derive the governing equation of motion and corresponding boundary conditions. A higher-order partial differential equation that is a typical characteristic of nonlocal strengthening model is developed, and the boundary conditions contain not only classical conditions but also non-classical higher-order conditions. Unlike previous studies which were only concerned with some conventional boundary constraints, we consider more general boundary conditions named elastic torsional spring supports. Such boundary conditions are between the simply supported and clamped ones, and they are closer to the actual constraints of existing engineering structures. Natural frequencies of micro-rods with new boundary constraints are determined via an eigenvalue method and compared with other results in the literature. It is shown that the nonlocal scale factor, thermal parameter, rigidity parameter and torsional spring coefficient play significant roles in free vibration of micro-rods. The research can provide a reference for a large class of boundary conditions ranging from simply supported to clamped micro-rods.     

考虑不确定性的大坝监测信息异常诊断方法及应用

大坝监测资料分析是一个充满不确定性的复杂非线性问题,常规的分析方法较少考虑监测信息中的不确定性问题,导致分析结果的合理性存疑。因此,基于信息熵理论的重要指标——近似熵研究大坝监测信息中的不确定性问题,利用实际监测数据选取近似熵算法的关键参数,进而评估大坝的运行状态。通过分析混凝土坝坝顶水平位移和土石坝测压管水位,发现近似熵算法能在若干监测信息不确定性条件下较有效地识别大坝监测数据的异常。     

某能源公司安全管理效率评价

某能源股份有限公司是我国上市煤炭公司,为评价其安全管理效率,采用数据包络(DEA)分析方法,以员工人数、资产总额、安全生产费为投入指标,以原煤产量、百万吨煤死亡率为产出指标,对其2007—2018年间的安全管理效率进行了评价。结果显示,某能源公司在研究期间的安全管理效率较为低下,但近5年来有提升的趋势,2018年安全管理实现DEA有效;安全管理无效的主要原因为纯技术效率和规模效率低下。为提高安全管理效率,该企业应在安全投入资源的匹配性和安全投入规模的合理性两个方面采取针对性措施。     

煤矿安全监控系统的发展简述

煤矿安全监控系统是煤矿日常安全管理和灾害防治不可或缺的安全装备,然而现有安全监控系统普遍存在网络结构可靠性差、抗干扰能力弱、数字化程度低、兼容性差、智能化水平低等问题。结合监控系统升级改造的具体要求,对我国煤矿安全监测监控系统的现状,包括存在的主要问题进行了论述,并对系统升级改造后的变化及未来的发展趋势进行了探讨。分析表明,基于工业太环网、数字总线双重冗余结构的新一代全数字式煤矿安全监控系统集多主通讯、智能传感、电磁兼容等多项关键技术于一体,满足监控系统数字化、智能化以及网络化的升级改造要求,也是未来监控系统的发展趋势。新系统的应用可有效提高煤矿的防灾抗灾能力,为煤矿的安全生产提供保障。